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Masters of Evil Chronology

https://en.wikipedia.org/wiki/Masters_of_Evil

Marvel Age Introductions by On-Sale Date
1964	MAY 05	AVN006	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp] [INTROMOEROS•Masters of Evil • Baron Zemo • Black Knight • The Melter • Radioactive Man][Paste-Pot Pete•Trapster]
1964	JUN 09	AVN007	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp][Loki][MOEROS•Masters of Evil • Baron Zemo • Enchantress • The Executioner]
1964	AUG 11	AVN009	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp] [INTROWonder Man][MOEROS•Masters of Evil • Baron Zemo • Enchantress • The Executioner]
1964	SEP 08	AVN010	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp] [INTROImmortus][MOEROS•Masters of Evil • Baron Zemo • Enchantress • The Executioner]
1965	FEB 11	AVN015	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp][MOEROS•Masters of Evil • Baron Zemo • Black Knight • Enchantress • The Executioner • The Melter]
1965	MAR 11	AVN016	The Avengers	[AVNROS•Captain America • Giant-Man • Iron Man • Mighty Thor • The Wasp] New Lineup[AVNROS•Captain America • Hawkeye • Quicksilver • Scarlet Witch] xo[Sub-Mariner][Immortus][Kang the Conquerer][Mole Man][MOEROS•Masters of Evil • Baron Zemo • Black Knight • Enchantress • The Executioner • The Melter]]
1968	MAY 9	AVN054	The Avengers	[AVNROS•Black Panther • Goliath • Hawkeye • The Wasp] •[Ultron][MOEROS•Masters of Evil • Klaw • The Melter • Radioactive Man • Whirlwind(Human Top)]
1968	JUN 11	AVN055	The Avengers	[AVNROS•Black Panther • Goliath • Hawkeye • The Wasp][MOEROS•Masters of Evil • Klaw • The Melter • Radioactive Man • Whirlwind(Human Top)

avn 83